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N-甲基咪唑衍生物的原位紫外光谱电化学行为
In situ UV Spectroscopy Studies on the Electrochemical Behavior of N-Methylimidazole Derivatives
【摘要】 用循环伏安法(CV)测定了寡聚酰胺单体N-甲基咪唑衍生物的电化学行为,探讨用原位紫外光谱法对电化学反应过程进行检测,观察到随极化电势的增加在紫外光谱中出现新的吸收峰,分析了N-甲基咪唑衍生物的还原历程.
【Abstract】 Cyclic voltammetry(CV)was used to investigate the electrochemical behavior of N-methylimidazole derivatives.The electroreduction process was monitored by in situ UV spectroscopy,a few new absorbance were observed with increase of polarization potential,and the mechanism of electrore-duction for the N-methylimidazole derivatives was discussed.
【关键词】 N-甲基咪唑衍生物;
紫外-可见光谱;
循环伏安;
原位紫外光谱电化学;
【Key words】 N-methylimidazole derivative; UV spectroscopy; cyclic voltammetry; in situ UV spectroelec-trochemistry;
【Key words】 N-methylimidazole derivative; UV spectroscopy; cyclic voltammetry; in situ UV spectroelec-trochemistry;
【基金】 国家自然科学基金(Nos.20473005,20573008)资助项目.
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2007年16期
- 【分类号】O626.23
- 【下载频次】284