节点文献
稀土与华法灵、水杨酸三元配合物的合成和抗凝血作用研究
Study on Syntheses and Anticoagulant Action of Rare Earth Ternary Complexes with Warfarinanion and Salicylate
【摘要】 用氯化稀土与华法灵钠、水杨酸钠在不同介质中制备了稀土三元配合物,所试验各种制备方法均可获得恒定组成的配合物REL2L′·2H2O(HL=华法灵离子:HL′=水杨酸离子)。通过元素分析、红外光谱、核磁共振氢谱、X射线衍射、摩尔电导、电子吸收光谱和溶解性试验对配合物进行了表征,抗凝血试验表明稀土三元配合物具有优良的抗凝血性质。
【Abstract】 The rare earth ternary complexes have been prepared with rare earth chlorides,warfarinanion so- dium and sodium salicylate.The above complexes have constant composition of REL2L’·2H2O (L= warfarinanion,L’=salicylate) prepared by different synthesis methods,and have been characterized by ele- mental analysis,IR,1H NMR spectra,X-ray diffraction,molar conductivity,electronic absorption spectrum and solubility.The rare earth ternary complexes all have nice anticoagulant action in related experiments.
【关键词】 稀土;
三元配合物;
华法灵;
水杨酸;
抗凝血作用;
【Key words】 rare earth; ternary complex; warfarinanion; salicylate; anticoagulant action;
【Key words】 rare earth; ternary complex; warfarinanion; salicylate; anticoagulant action;
【基金】 甘肃省自然科学基金(No.3zs051-A25-021);甘肃省高分子材料重点实验室资助项目。
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2007年08期
- 【分类号】R914;R96
- 【被引频次】35
- 【下载频次】293