节点文献
四氯化锡配位条件下的烃基化反应
Alkylation reaction using tin tetrachloride coordination complex
【摘要】 先将四氯化锡与适量醚类化合物形成配合物,再与格氏试剂发生交换反应,可得到高品质和较高收率的三环己基氯化锡产品。探讨了溶剂种类、时间、温度、原料配比等因素对格氏试剂和锡的烷基化反应的影响。
【Abstract】 A high-quality and high-yield tricyclohexyltin chloride product was obtained via alkylation between the Grignard reagent and the complexes formed by the reaction of tin tetrachloride and appropriate ethers.The influence of reaction temperature and time,solvent and the molar ratio of starting materials on alkylation of tin with the Grignard reagent was investigated.
- 【文献出处】 化学试剂 ,Chemical Reagents , 编辑部邮箱 ,2007年05期
- 【分类号】O621.25
- 【下载频次】183