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两个新二茂铁酰基硫脲衍生物的合成与表征
Synthesis and Characterization of Two Novel Ferrocenoyl Thiourea Derivatives
【摘要】 以二茂铁为原料,首先分别合成了1-二茂铁甲酸和1,1-’二茂铁二甲酸,然后通过酰化、缩合等一系列反应,得到了二个新的二茂铁酰基硫脲衍生物,并通过元素分析I、R1、HNMR等手段对其进行了表征,另外,初步试验证实二者具有良好的配位性能和植物调节活性.
【Abstract】 1-ferrocenecarboxylate and 1,1’-ferrocenedicarboxylate were synthesized with ferrocene as raw material, and then two novel ferrocenoyl thiourea derivativesⅠand Ⅱ were obtained through a series of acylation and condensation from them.Ⅰand Ⅱ were characterized by elemental analysis,IR and 1HNMR spectra.In addition,the primary experiments show that Ⅰand Ⅱ have better plant-growth regulatory activity and coordination properties.
【关键词】 二茂铁;
1-二茂铁甲酸;
1,1-’二茂铁二甲酸;
酰基硫脲;
合成;
【Key words】 ferrocene; 1-ferrocenecarboxylate; 1,1-ferrocenedicarboxylate; acetyl thiourea; synthesis;
【Key words】 ferrocene; 1-ferrocenecarboxylate; 1,1-ferrocenedicarboxylate; acetyl thiourea; synthesis;
【基金】 河南省教育厅自然科学研究项目(2006150035)
- 【文献出处】 河南科学 ,Henan Science , 编辑部邮箱 ,2007年02期
- 【分类号】O627.81
- 【被引频次】2
- 【下载频次】190