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两个新二茂铁酰基硫脲衍生物的合成与表征

Synthesis and Characterization of Two Novel Ferrocenoyl Thiourea Derivatives

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【作者】 杨怀霞王利平孟祥茹

【Author】 YANG Huai-xia1,2,WANG Li-ping1,MENG Xiang-ru1(1.Department of Chemistry,Zhengzhou University,Zhengzhou 450052,China; 2.Department of Chinese Medicine,Henan College of Traditional Chinese Medicine,Zhengzhou 450008,China)

【机构】 郑州大学化学系郑州大学化学系 郑州450052河南中医学院药学院郑州450008郑州450052

【摘要】 以二茂铁为原料,首先分别合成了1-二茂铁甲酸和1,1-’二茂铁二甲酸,然后通过酰化、缩合等一系列反应,得到了二个新的二茂铁酰基硫脲衍生物,并通过元素分析I、R1、HNMR等手段对其进行了表征,另外,初步试验证实二者具有良好的配位性能和植物调节活性.

【Abstract】 1-ferrocenecarboxylate and 1,1’-ferrocenedicarboxylate were synthesized with ferrocene as raw material, and then two novel ferrocenoyl thiourea derivativesⅠand Ⅱ were obtained through a series of acylation and condensation from them.Ⅰand Ⅱ were characterized by elemental analysis,IR and 1HNMR spectra.In addition,the primary experiments show that Ⅰand Ⅱ have better plant-growth regulatory activity and coordination properties.

【基金】 河南省教育厅自然科学研究项目(2006150035)
  • 【分类号】O627.81
  • 【被引频次】2
  • 【下载频次】190
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