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玄武岩纤维表面涂层改性研究

Study on Sizing Modification of Basalt Fibers

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【作者】 曹海琳张春红张志谦高原

【Author】 CAO Hai-lin1,3,ZHANG Chun-hong2, ZHANG Zhi-qian1,GAO Yuan1(1.Harbin Institute of Technology,Harbin 150001,China;2.Harbin Engineering University,Harbin 150001,China;3.Shenzhen Tech-Innovation lnternational,Key Laboratory of Composites Materials,Shenzhen 518057,China)

【机构】 哈尔滨工业大学哈尔滨工程大学哈尔滨工业大学 哈尔滨150001深圳国际技术创新研究院复合材料重点实验室广东深圳518057哈尔滨150001

【摘要】 采用溶胶-凝胶技术制备有机/无机纳米杂化涂层材料,通过红外光谱和原子力显微镜技术对该材料进行表征分析,结果表明合成了环氧/SiO2纳米杂化材料。采用合成的纳米杂化浆料对玄武岩纤维进行表面改性,通过纤维表面形貌、纤维复丝拉伸强度和复合材料层间剪切强度分析,研究玄武岩纤维表面涂层改性效果。试验结果表明:采用适当浓度的涂层溶液对玄武岩纤维进行表面改性可以有效的增加纤维表面粗糙度,提高纤维复丝拉伸强度,改善复合材料界面粘接强度,说明玄武岩纤维表面涂敷有机/无机纳米杂化涂层的改性方法是确实有效的。

【Abstract】 The organic/inorganic hybrid sizing was synthesized by sol-gel method.The IR and AFM analysis results indicated that the epoxy/SiO2 nano-hybrid material was synthesized.The basalt fibers were surface modified by organic/inorganic nano-hybrid sizing.The surface morphology of basalt fibers,the multifilament yarn tensile strength and the ILSS of its composites were investigated.The results indicated that when the basalt fibers were modified by hybrid sizing with optimum concentration the surface morphology of the fiber was rougher and the tensile strength was increased,meanwhile the ILSS of its composites was improved.All of these research proved that the sizing modification using organic/inorganic nano-hybrid sizing was an effective method for improving basalt fiber and its composites properties.

【基金】 国家自然科学基金资助项目(50503007)
  • 【文献出处】 航空材料学报 ,Journal of Aeronautical Materials , 编辑部邮箱 ,2007年05期
  • 【分类号】TB304
  • 【被引频次】46
  • 【下载频次】1010
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