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Surface reaction of Bacillus cereus biomass and its biosorption for lead and copper ions

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【Author】 PAN Jian-hua, LIU Rui-xia, TANG Hong-xiao State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

【摘要】 <正>In this study, the surface chemical functional groups of Bacillus cereus biomass were identified by Fourier transform infrared (FTIR) analytical technique. It had been shown that the B. cereus cells mainly contained carboxyl, hydroxyl, phosphate, amino and amide functional groups. The potentiometric titration was conducted to explain the surface acid-base properties of aqueous B. cereus biomass. The computer program FITEQL 4.0 was used to perform the model calculations. The optimization results indicated that three sites-three pKas model, which assumed the cell surface to have three distinct types of surface organic functional groups based on the IR analysis results, simulated the experimental results very well. Moreover, batch adsorption experiments were performed to investigate biosorption behavior of Cu(II) and Pb(II) ions onto the biomass. Obviously, the adsorption equilibrium data for the two ions were reasonably described by typical Langmuir isotherm.

【Abstract】 In this study, the surface chemical functional groups of Bacillus cereus biomass were identified by Fourier transform infrared (FTIR) analytical technique. It had been shown that the B. cereus cells mainly contained carboxyl, hydroxyl, phosphate, amino and amide functional groups. The potentiometric titration was conducted to explain the surface acid-base properties of aqueous B. cereus biomass. The computer program FITEQL 4.0 was used to perform the model calculations. The optimization results indicated that three sites-three pKas model, which assumed the cell surface to have three distinct types of surface organic functional groups based on the IR analysis results, simulated the experimental results very well. Moreover, batch adsorption experiments were performed to investigate biosorption behavior of Cu(II) and Pb(II) ions onto the biomass. Obviously, the adsorption equilibrium data for the two ions were reasonably described by typical Langmuir isotherm.

【基金】 Project supported by the National Natural Science Foundation of China (No. 20537020, 20677073).
  • 【文献出处】 Journal of Environmental Sciences ,环境科学学报(英文版) , 编辑部邮箱 ,2007年04期
  • 【分类号】X172
  • 【被引频次】32
  • 【下载频次】63
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