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疏水改性阳离子型丙烯酰胺共聚物的微结构与絮凝性能

Microstructure and flocculation properties of hydrophobically associating acrylamide-modified cationic copolymer

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【作者】 钟传蓉何文琼赖立罗平亚

【Author】 ZHONG Chuanrong 1,2,HE Wenqiong 2,LAI Li 2, LUO Pingya 1 ( 1State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Xindu 610500, Sichuan, China; 2School of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, Sichuan, China)

【机构】 西南石油大学油气藏地质及开发工程国家重点实验室成都理工大学材料与化学化工学院西南石油大学油气藏地质及开发工程国家重点实验室 四川新都610500成都理工大学材料与化学化工学院四川成都610059四川新都610500

【Abstract】 The hydrophobically associating copolymers,poly(BS/AM/DMDAAC)(PBAD) were synthesized from acrylamide (AM),butyl styrene (BS) and dimethyldiallyammonium chloride (DMDAAC) by the micellar free radical copolymerization technique.The copolymers were characterized with UV and FT-IR.The atomic force microscope(AFM) measurement showed that aggregates had been formed in the aqueous solution of 0.005 g.dl -1 PBAD, and with the increase of PBAD concentration, the number and size of aggregates increased due to the intermolecular hydrophobic association of butylphenyl groups.The optimum flocculant concentration of PBAD was 0.005 g·dl -1 in the aqueous solution of 3% diatomite and the transmittance was 96.5%.The NaCl concentration obviously influenced the bridging and adsorption behavior of the copolymer for celite suspensions, and calcium and aluminium ions strengthened the flocculation effect of the polymer.

【基金】 中国博士后科学基金项目(20060391033);国家重点基础研究发展计划项目(2005CB221302)~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2007年08期
  • 【分类号】X703.5
  • 【被引频次】16
  • 【下载频次】356
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