节点文献
疏水改性阳离子型丙烯酰胺共聚物的微结构与絮凝性能
Microstructure and flocculation properties of hydrophobically associating acrylamide-modified cationic copolymer
【Abstract】 The hydrophobically associating copolymers,poly(BS/AM/DMDAAC)(PBAD) were synthesized from acrylamide (AM),butyl styrene (BS) and dimethyldiallyammonium chloride (DMDAAC) by the micellar free radical copolymerization technique.The copolymers were characterized with UV and FT-IR.The atomic force microscope(AFM) measurement showed that aggregates had been formed in the aqueous solution of 0.005 g.dl -1 PBAD, and with the increase of PBAD concentration, the number and size of aggregates increased due to the intermolecular hydrophobic association of butylphenyl groups.The optimum flocculant concentration of PBAD was 0.005 g·dl -1 in the aqueous solution of 3% diatomite and the transmittance was 96.5%.The NaCl concentration obviously influenced the bridging and adsorption behavior of the copolymer for celite suspensions, and calcium and aluminium ions strengthened the flocculation effect of the polymer.
【Key words】 butyl styrene; hydrophobically associating; solution microstructure; cationic flocculating agent;
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2007年08期
- 【分类号】X703.5
- 【被引频次】16
- 【下载频次】356