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微波共沉淀法制备锂离子电池正极材料LiNi0.8Co0.2O2

Preparation and electrochemical properties of LiNi0.8Co0.2O2 cathode material by microwave coprecipitation method

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【作者】 王亮何雨石张晓鸣廖小珍马紫峰

【Author】 WANG Liang,HE Yushi,ZHANG Xiaoming,LIAO Xiaozhen,MA Zifeng(Department of Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China)

【机构】 上海交通大学化学工程系上海交通大学化学工程系 上海200240上海200240

【Abstract】 The microwave coprecipitation method was used to synthesize α-Ni0.8Co0.2(OH)2 precursor for preparing LiNi0.8Co0.2O2 cathode material.The precursor α-Ni0.8Co0.2(OH)2 was mixed with LiOH·H2O and then calcined in O2 for 10 h at different temperatures(700℃,800℃,900℃).XRD,SEM analyses and electrochemical tests were used to study the physical and electrochemical performance of the cathode material.With increasing calcination temperature,the characteristic peaks of the cathode materials became stronger and sharper,corresponding to a perfect crystalization.The results of electrochemical tests indicate that the sample LiNi0.8Co0.2O2 (900℃)showed excellent electrochemical properties,with an initial discharge capacity of 189.1 mA·h·g-1 and an initial discharge efficiency of 92.5%.After 30 cycles,the discharge capacity was still 148 mA·h·g-1,showing good cyclic stability.

【基金】 国家自然科学基金项目(20476055);教育部新世纪优秀人才支持计划项目(2004)~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2007年04期
  • 【分类号】TM912
  • 【被引频次】5
  • 【下载频次】320
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