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环己苯过充添加剂在锂离子电池中的应用

Application of cyclohexyl benzene as overcharge protection additive in lithium ion batteries

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【作者】 唐致远刘强陈玉红贺艳兵

【Author】 TANG Zhiyuan,LIU Qiang,CHEN Yuhong,HE Yanbing (Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072,China)

【机构】 天津大学化工学院应用化学系天津大学化工学院应用化学系 天津300072天津300072

【Abstract】 The application of cyclohexyl benzene(CHB)as the overcharge protection additive in lithium ion batteries was analyzed.Through 1C overcharge testing,battery performance testing, electrochemical impedance testing,electrolyte conductivity and self-discharge testing,the use of cyclohexyl benzene as the overcharge protection additive and the effect of cyclohexyl benzene on battery performance were investigated.The possible mechanism of cyclohexyl benzene as the overcharge protection addtive was discussed.When the content of cyclohexyl benzene was more than 5%(mass),the battery could be protected from explosion.When the content of the cyclohexyl benzene exceeded 7%(mass),a detrimental effect on battery performance was found.Cyclohexyl benzene could also decrease electrolyte conductivity,leading to increased self-discharge.The proper content of cyclohexyl benzene was between 5%(mass) and 7%(mass).

【基金】 国家自然科学基金项目(20273047);教育部博士点重点基金项目(20020056045)。~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2007年02期
  • 【分类号】TM912.9
  • 【被引频次】10
  • 【下载频次】301
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