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铑-钌双金属催化体系氢化丁腈橡胶的性能

Properties of hydrogenated nitrile-butadiene rubber catalyzed by novel Rh-Ru bimetallic system

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【作者】 姚明张东恒徐瑞清许贵显钟毓镇

【Author】 Yao Ming~1,Zhang Dongheng~1,Xu Ruiqing~1,Hsu Kueihsien~2,Zhong Yuzhen~2(1.College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Nantex Chemical Industry Company Limited,Kaohsing 832,China)

【机构】 北京化工大学材料科学与工程学院南帝化学工业股份有限公司南帝化学工业股份有限公司 北京100029北京100029台湾高雄832

【摘要】 用新型铑-钌双金属催化剂制备了氢化丁腈橡胶(HNBR),分析了产物基本性能,并与国外同类产品进行了对比。结果表明,HNBR的相对分子质量较基础胶有所提高;与德国Bayer公司的Ther-ban A 3406和日本Zeon公司的Zetpol 2000 L相比,其物理机械性能和耐油性能基本相当,在通常的剪切速率范围内的流变性能也相近。

【Abstract】 The hydrogenated nitrile-butadiene rubber(HNBR) catalyzed by novel Rh-Ru bimetallic system was prepared,its general properties were(analyzed) and compared with Therban A 3406 by Bayer corporation and Zetpol 2000 L by Zeon corporation.The results showed that the relative molecular mass of domestic HNBR was a little increase compared to nitrile-butadiene rubber,its mechanical properties were superior to those of Therban A 3406 and Zetpol 2000 L,and their oil resistance and theological properties at 130 ℃ and(140 ℃) in the range of shear rate 0~(100 s-1) were similar.

  • 【文献出处】 合成橡胶工业 ,China Synthetic Rubber Industry , 编辑部邮箱 ,2007年01期
  • 【分类号】TQ333.7
  • 【被引频次】5
  • 【下载频次】182
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