【摘要】 以对叔丁基杯[4]芳烃为起始原料,合成了25-羟基-26,27,28-三丁氧基对叔丁基杯[4]芳烃(2)和25-[(乙氧基羰基)甲氧基]-26,27,28-三丁氧基对叔丁基杯[4]芳烃(3),2和3的结构经1HNMR和IR表征。通过正交实验[L16(45)和L9(33)]优化了实验条件,使3的总收率提高到60%。更多还原

【Abstract】 25-Hydroxy-26,27,28-tributyloxy-p-tert-butyl-calix[4]arene(2) and 25-[(ethoxycarbonyl)methoxy]-26,27,28-tributyloxy-p-tert-butyl-calix[4]arene(3) were synthesized. The structures of 2 and 3 were characterized by 1H NMR and IR. The reacion conditions for synthesizing 3 were optimized by orthogonal tests[L16(45) and L9(33)]. The total yield of 3 was 60% under the optimum reaction conditions.更多还原