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葡萄糖苯酚树脂胶粘剂的合成
Synthesis of glucose-phenol resin adhesive
【摘要】 以葡萄糖代替甲醛,在碱性条件下合成了葡萄糖苯酚树脂胶粘剂。用红外光谱(IR)对其结构进行了分析,并通过正交实验获得了该树脂合成的最佳反应条件:pH=11,n(葡萄糖):n(苯酚)=8:1,反应温度120℃,催化剂用量14.3%,反血时间4 h;同时对树脂的固化条件进行了系统研究。
【Abstract】 In alkali condition,glucose-phenol resin adhesive by using D-glucose instead of formaldehyde was prepared successfully.The structure was characterized by IR,and through orthogonal experiment the optimum conditions of the reaction were obtained:pH value is 11,molar ratio of glucose to phenol is 8:1,the weight of catalyst is 14.3%(percent of the weight of D-glucose),reaction temperature is 120℃,reaction time is 4 h,and the curing reaction of the resin was also studied by this method.
【基金】 陕西省自然科学基金(2003B19)资助项目。
- 【文献出处】 中国胶粘剂 ,China Adhesives , 编辑部邮箱 ,2007年02期
- 【分类号】TQ433.431
- 【被引频次】21
- 【下载频次】383