【摘要】 通过研究内层电子结合能及其氧化态的变化,X射线光电子能谱(XPS)可以鉴别元素种类和价态、测定元素的相对含量、了解中心离子与配位原子的相互作用和验证量子化学理论。XPS已成为研究配合物中配位位点、电荷分配和配合物结构的有力工具。更多还原

【Abstract】 X-ray photoelectron spectroscopy (XPS) provides information about the core-level binding energies and oxidation states of complexes. It can be used to identify the species and valence states of elements, measure the relative content of elements, investigate the interaction between ligands and central ions, and verify the results obtained by quantum chemistry theory. XPS has been found to be a powerful tool for identifying coordination site, evaluating charge redistribution, and characterizing geometry of complexes.更多还原