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偶氮氯膦-mA分光光度法测定合金中稀土总量
Spectrophotometric Determination of ∑RE in Alloy Steel with CPA-mA
【摘要】 在pH0.7~1.8的酸性溶液中,稀土元素和偶氮氯膦-mA生成紫色络合物,这个反应体系可以用来进行合金钢中稀土元素的比色测定,溶液中共存离子铬、锰、镍、铁等对分析有干扰,通过对试样进行特殊处理,可去除干扰元素,然后直接进行比色,结果满意。
【Abstract】 Purple multi-component complex of ∑Re and CPA-mA forms in the solution of PH0.7-1.8,this reaction system can be used for spectrophotometric determination of ∑Re in steel alloy,coexisted ions such as Cr6+、Mn2+、Ni2+、Fe3+ interfere determination.Putting away these interfering elements though special processing,we can then nesslerize directly.The results are satisfying.
- 【文献出处】 锅炉制造 ,Boiler Manufacturing , 编辑部邮箱 ,2007年02期
- 【分类号】TG115.335
- 【被引频次】1
- 【下载频次】70