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Basic Ionic Liquid: A Reusable Catalyst for Knoevenagel Condensation in Aqueous Media

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【Author】 GAO Guo-hua, LU Liang, ZOU Ting, GAO Jin-bao, LIU Ye and HE Ming-yuan Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

【Abstract】 An efficient, environmentally friendly procedure was developed for the condensation of aldehydes/ketones and activated methylene compounds with basic ionic liquid as the catalyst in water. This basic ionic liquid catalyst has a very high activity for Knoevenagel condensation to give the corresponding products in 70%—97% isolated yields under mild conditions. The basic ionic liquid catalyst in aqueous system can be reused for six times without any significant loss of activity.

【基金】 the National Natural Science Foundation of China(No 20533010)
  • 【文献出处】 Chemical Research in Chinese Universities ,高等学校化学研究(英文版) , 编辑部邮箱 ,2007年02期
  • 【分类号】O643.32
  • 【被引频次】10
  • 【下载频次】154
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