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含TiO2/(RSiO1.5)8复合物涂层的光活性与抗老化性能

Study on the Photocatalysis and Anti-Aging Properties of Organic Coatings Containing TiO2/(RSiO1.5)8 Particles

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【作者】 温永向刘安华张利利刘瑶宇邵剑

【Author】 WEN Yong-xiang1,LIU An-hua2,ZHANG Li-li2,LIU Yao-yu3, SHAO Jian2 (1.Guangzhou Sihang Institute of Engineering Technology,Guangzhou 510230,China;2.Institute of Materials,South China University of Technology,Guangzhou 510640,China;3.Zhuhai Compus,Beijing Normal University,Zhuhai 519085,China)

【机构】 广州四航工程技术研究院华南理工大学材料学院北京师范大学珠海校区华南理工大学材料学院 广东广州510230广东广州510640广东珠海519085

【摘要】 通过Sol-Gel法,以(RSiO1.5)8作为载体,将纳米TiO2分散到(RSiO1.5)8网络里制得TiO2/(RSiO1.5)8纳米复合光活性粒子,并将其分散到醇酸树脂中制成含TiO2/(RSiO1.5)8的有机涂层。实验结果表明,TiO2/(RSiO1.5)8复合粒子比纯TiO2粒子拥有更强的光催化性能,含TiO2/(RSiO1.5)8复合物的有机涂层比只含有TiO2的有机涂层具有更好的抗老化性能。

【Abstract】 By means of sol-gel methods,TiO2/(RSiO1.5)8 composite photocatalyst particles were prepared at low temperature.With the composites dispersing into alkyd resin,nanocomposite organic coatings were yielded.The light absorption of the particles was recorded by UV-VIS spectrophotometer,and it shows TiO2/(RSiO1.5)8 particles have a better UV light absorption than titanium dioxide.And under UV light irradiating,the TiO2/(RSiO1.5)8/resin coatings have a more efficient photocatalysis in degrading methylene blue.The anti-aging ability of the coatings was characterized by Surface Gloss Equipment and Scanning Electron Microscopy(SEM),and it indicates the coatings containing TiO2/(RSiO1.5)8 particles have a better anti-aging ability.The addition of(RSiO1.5)8 particles can enhance the photocatalytic activation,and also prevent the organic matrix from degrading.

【基金】 国家自然科学基金资助项目(29974009)
  • 【文献出处】 高分子材料科学与工程 ,Polymer Materials Science & Engineering , 编辑部邮箱 ,2007年04期
  • 【分类号】TG174.4;TB383.1
  • 【下载频次】166
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