【摘要】 合成了一种新型的喹啉衍生物类单体2,7,7-三甲基-3-乙氧羰基-4-(4-丙烯酰胺苯基)-5-氧代-1,4,5,6,7,8-六氢喹啉(TEOHQ),并通过原子转移自由基聚合(ATRP)的方法制备了TEOHQ与苯乙烯的共聚物。以元素分析,GPC,1H-NMR及荧光发射光谱表征了共聚物。数均分子量(M-n)随转化率的线性增加及相对较窄的分子量分布(M-w/M-n)证明了聚合的可控性。同时,利用Mayo-Lewis公式测定了两种单体的竞聚率。最后,从共聚物荧光发射光谱图中显示出共聚物的最大发射峰位于436 nm处,相对于425 nm处单体TEOHQ的最大发射峰发生了11nm的红移。更多还原

【Abstract】 A novel quinoline derivative monomer 2,2,7-trimethyl-3-ethoxycarbonyl-4-(4-acrylamidephenyl)-5-oxo-1,4,5,6,7,8hexhydricquinoline(TEOHQ) was synthesized.The copolymers were prepared by atom transfer radical copolymerization of TEOHQ with styrene.Element analysis,GPC,1H-NMR and fluorescent emission spectroscopy were used to characterize copolymers.The linear increase of number average molecular weight(n) versus conversion and the relatively narrow molecular weight distribution(w/n) confirmed that the copolymerization is controllable.In addition,the reactivity ratios of the monomers TEOHQ and styrene were also measured by the method of Mayo-Lewis.Moreover,we investigated the fluorescent property of the obtained copolymers and these copolymers were exhibited fluorescent emission maxima at 436 nm,there is 11nm red-shift comparing to the monomer TEOHQ(425nm).更多还原