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多枝桉乙酸法蒸煮特性以及组分反应动力学模型的研究

Study on Cooking Property of E.Viminalis Wood and the Kinetics of the Fraction in Acetic Acid-H2SO4 Media

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【作者】 马晓娟敖日格勒黄国红沙舟李燕

【Author】 Ma Xiaojuan Aorigele Huang Guohong Sha Zhou Li Yan (State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640)

【机构】 华南理工大学制浆造纸工程国家重点实验室华南理工大学制浆造纸工程国家重点实验室 广州510640广州510640

【摘要】 动力学模型是研究反应动力学的一个很有力的工具。试验采用乙酸法对多枝桉木片进行了蒸煮。在硫酸用量为1.0%、2.0%、2.5%、3.0%的条件下,研究了其蒸煮特性。并根据残余固体,以及残余固体中Klason木素含量的变化,提出了残余固体以及残余固体中Klason木素动力学模型方程。深入讨论了浓度、时间对蒸煮过程中组分:残余固体、残余固体中Klason木素、乙酸木素以及提取糖的的影响。

【Abstract】 Kinetic models were developed to give an interpretation of several phenomena in wood fraction. Experimental data (obtained in wood treatments at normal boiling temperature with 90% acetic acid solutions containing 1.0%~3.0% H2SO4), were used to develop kinetic equations for: (1)solid residue yield ,(2) solid residue composition:lignin. By means of empirical equations, the kinetic parameters were correlated with the catalyst H2SO4 concentration used in the various experiments, leading to generalized models which are useful for technical and economic evaluation of the studied process.

  • 【文献出处】 造纸科学与技术 ,Paper Science & Technology , 编辑部邮箱 ,2007年01期
  • 【分类号】TS743.1
  • 【被引频次】1
  • 【下载频次】85
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