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高温合成NaY沸石

High Temperature Synthesis of NaY Zeolite

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【作者】 熊晓云李彩今于红黄世英梁德声肖丰收李守贵

【Author】 XIONG Xiao-Yun,LI Cai-Jin,DING Hong,HUANG Shi-Ying,LIANG De-Sheng,XIAO Feng-Shou,LI Shou-Gui(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130012,China)

【机构】 吉林大学无机合成与制备化学国家重点实验室吉林大学无机合成与制备化学国家重点实验室 长春130012长春130012

【Abstract】 This work describes a novel method to synthesize NaY zeolite at high temperature(100-140 ℃)by using NaY seeds solution as a silica source,which is also a method for the activation of silica source in the synthesis of NaY zeolite.Conventionally,the synthesis temperature of NaY zeolite from water glass is about 100 ℃,and higher temperature(>100 ℃)leads to the formation of impurity.However,this work shows that high-temperature synthesis(100-140 ℃)still exhibits a pure phase NaY.It is very interesting that,compared with conventional temperature,high-temperature in the synthesis of NaY zeolite has obvious advantages such as short crystallization time and high n(Si)/n(Al)ratio in the product.More importantly,this method is possible to extend to the synthesis of NaA,NaX,Ω,ECR-1and MOR.

【基金】 国家“九七三”计划(批准号:2003CB615802)资助.
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2007年09期
  • 【分类号】TQ426.6
  • 【被引频次】10
  • 【下载频次】494
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