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立方规则孔道结构含锆介孔氧化硅的合成与表征
Preparation and Structure Characterization of Ordered Cubic Zr-doped Mesoporous Silica by EISA Method
【Abstract】 Highly ordered cubic Zr-doped mesoporous silica was directly prepared with Evaporation-Induced Self Assembly method(EISA) with triblock copolymers(Pluronic P123) as the structure-directing agents.The mesoporous material was characterized via small-angle powder X-ray diffraction(XRD),transmission electron microscopy(TEM),and nitrogen adsorption.The results show that the product has a face-centered cubic structure with space group of Fd3m.N2 sorption revealed that the Zr-doped mesoporous silica has not only ordered structures,but also high surface area(550 m2/g),large pore volume(0.66 cm3/g),as well as uniform pore size(4.0 nm).
【关键词】 介孔二氧化硅;
氧化锆;
立方相;
溶剂挥发法;
【Key words】 Mesoporous silica; Zirconia; Cubic phase; Evaporation-induced self-assembly(EISA);
【Key words】 Mesoporous silica; Zirconia; Cubic phase; Evaporation-induced self-assembly(EISA);
【基金】 国家自然科学基金(批准号:20273026)资助
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2007年08期
- 【分类号】O614
- 【被引频次】2
- 【下载频次】211