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立方规则孔道结构含锆介孔氧化硅的合成与表征

Preparation and Structure Characterization of Ordered Cubic Zr-doped Mesoporous Silica by EISA Method

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【作者】 储彬王润伟沈启慧陈璐万利丰朱广山裘式纶

【Author】 CHU Bin,WANG Run-Wei,SHEN Qi-Hui,CHEN Lu,WAN Li-Feng,ZHU Guang-Shan,QIU Shi-Lun*(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin Univesity,Changchun 130012,China)

【机构】 吉林大学无机合成与制备化学国家重点实验室吉林大学无机合成与制备化学国家重点实验室 长春130012长春130012

【Abstract】 Highly ordered cubic Zr-doped mesoporous silica was directly prepared with Evaporation-Induced Self Assembly method(EISA) with triblock copolymers(Pluronic P123) as the structure-directing agents.The mesoporous material was characterized via small-angle powder X-ray diffraction(XRD),transmission electron microscopy(TEM),and nitrogen adsorption.The results show that the product has a face-centered cubic structure with space group of Fd3m.N2 sorption revealed that the Zr-doped mesoporous silica has not only ordered structures,but also high surface area(550 m2/g),large pore volume(0.66 cm3/g),as well as uniform pore size(4.0 nm).

【基金】 国家自然科学基金(批准号:20273026)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2007年08期
  • 【分类号】O614
  • 【被引频次】2
  • 【下载频次】211
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