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气体NO/SO2/N2/O2等离子体反应机理及动力学分析

MECHANISM AND KINETIC ANALYSIS OF NO/SO2/N2/O2 NON-THERMAL PLASMA DISSOCIATION REACTION PROCESS

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【作者】 李婷婷王心亮魏冬香魏燕丽顾璠

【Author】 LI Ting-Ting WANG Xin-Liang WEI Dong-Xiang WEI Yan-Li GU Fan (Education Ministry Key Laboratory on Clean Coal Power Generation and Combustion Technology,Southeast University,Nanjing 210096,China)

【机构】 东南大学洁净煤发电及燃烧技术教育部重点实验室东南大学洁净煤发电及燃烧技术教育部重点实验室 江苏 南京 210096江苏 南京 210096

【摘要】 本文研究了在低温等离子体条件下,电子碰撞NO/SO2/N2/O2气体引发离解反应的反应机理。应用碰撞理论和波尔兹曼方程分析,对能量分布函数及反应速率常数进行数值模拟,得到离解反应速率常数与温度的曲线,分析预报各反应过程及表现。最后将速率常数拟合为Arrhenius公式的形式。

【Abstract】 Mechanism of the dissociation reactions of NO/SO2/N2/O2 gaseous molecules in non- thermal plasma was investigated.Energy distribution function and chemical reaction rate coefficients were calculated through Boltzmann equation analysis and collision theory.The rate coefficients for electron collisions were fitted to Arrhenius form.The relation between chemical reaction rate and electron temperature was presented to judge the importance of each reaction and to predict the process of gaseous chemical reaction.

  • 【文献出处】 工程热物理学报 ,Journal of Engineering Thermophysics , 编辑部邮箱 ,2007年03期
  • 【分类号】X701
  • 【被引频次】14
  • 【下载频次】437
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