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X70管线钢在近中性及高pH值溶液中的电化学行为和SCC敏感性
ELECTROCHEMICAL BEHAVIOUR AND SCC SUSCEPTIBILITY OF PIPELINE STEEL X70 IN NEAR-NEUTRAL AND HIGH pH SOLUTIONS
【摘要】 采用动电位极化曲线测试法研究了温度、通气条件和pH值对X70管线钢在NS4溶液和0.5 mol/LNa2CO3+1 mol/L NaHCO3溶液中的电化学极化行为的影响,并用慢应变速率试验(SSRT)研究了X70管线钢在这些溶液中的应力腐蚀破裂(SCC)敏感性。结果表明,X70管线钢在NS4溶液中不出现活化—钝化转变区,随外加电位负移,SCC敏感性增加,表现出氢致破裂(HIC)的特征;在0.5 mol/L Na2CO3+1 mol/L NaHCO3高pH值溶液中出现活化—钝化转变区,在阴极极化区,也表现出氢致破裂(HIC)的特征,但在阳极极化区,发生的是阳极溶解型应力腐蚀破裂(ADSCC)。
【Abstract】 The influence of temperature,aerated condition and pH value on the electrochemical behavior and stress corrosion cracking(SCC) susceptibility of X70 pipeline steel in NS4 solution and 0.5 mol/L Na2CO3+1 mol/L NaHCO3 solution was investigated using potentiodynamic polarization measurements and slow strain rate tests(SSRT).In NS4 solution,active-passive transition behavior did not appear and SCC susceptibility increased with the negative movement of applied potential,indicating character of hydrogen induced cracking(HIC).In 0.5 mol/L Na2CO3+1 mol/L NaHCO3 solution,active-passive transition behavior was found in the potentiodynamic polarization curves,character of hydrogen induced cracking(HIC) was shown in cathodic polarization region and anodic dissolution SCC(ADSCC) occurred in anodic polarization region.
【Key words】 Pipeline steel; High-pH solution; NS4 solution; Electrochemical behavior; SCC susceptibility;
- 【文献出处】 腐蚀与防护 ,Corrosion & Protection , 编辑部邮箱 ,2007年01期
- 【分类号】TG172.6
- 【被引频次】20
- 【下载频次】370