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改性沸石处理高岭土洗选废水的实验研究

The Treatment of Wastewater from Kaolin Beneficiation with Surfactant-Modified Zeolite

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【作者】 刘钦甫; 李东勇; 杜娟; 刘龙涛; 侯丽华;

【Author】 Liu Qinfu1 Li Dongyong1 Du Juan2 Liu Longtao1 Hou Lihua1 (1 National Key Laboratory of Coal Resources and Safety Mining, China University of Mining and Technology (Beijing), Beijing 100083; 2 School of Environmental Engineering, Aanhui Institute of Architecture & Industry, Hefei 230009)

【机构】 中国矿业大学煤炭资源与安全开采国家重点实验室; 安徽建筑工业学院环境工程学院; 中国矿业大学煤炭资源与安全开采国家重点实验室 北京100083; 北京100083; 安徽合肥230009;

【摘要】 采用改性沸石处理高岭土洗选废水。研究表明:对于200ml洗选废水,当改性沸石用量为5g、振荡反应20min后,改性沸石对洗选废水中CODCr的最大去除率可达94%,出水值达到国家一级排放标准;吸附脱色率达到79%,出水值可达国家二级排放标准;对铁的最佳去除率超过70%。改性沸石对CODCr的去除,主要依靠其极化表面与有机分子的极性官能团发生的强吸附反应;而对色度的去除,为其对铁和CODCr去除作用的综合结果。改性沸石对有机质的吸附选择性,要大于铁。

【Abstract】 The treatment of wastewater from kaolin benefi ciation with surfactant-modifi ed zeolite was experimentally investigated. The results showed that the removal ratios of CODcr are up to 94% and can meet grade one of National Integrated Discharge Standard. The decolouring ratios reach to 79%, so that the treated water can meet the grade two of National Integrated Discharge Standard. Moreover, the modif ied zeolite also showed good results for iron removal from wastewater. The removal of CODcr by modifi ed zeolite attribute to the strong absorption of the polar group of organic molecules on the polar surface of modif ied zeolite, but decolouring attribute to the combined effects of both removal of CODcr and iron. The modifi ed zeolite absorbs selectively organic matter prior to iron.

  • 【文献出处】 非金属矿 ,Non-Metallic Mines , 编辑部邮箱 ,2007年04期
  • 【分类号】X703
  • 【被引频次】2
  • 【下载频次】187
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