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壳聚糖及其衍生物对染料废水的脱色研究

Decolorization of Dyeing Wastewater Using Chitosan Materials

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【作者】 陈忻孙恢礼潘嘉慧

【Author】 CHEN Xin~(1,2,3) SUN Hui-li~(1,2) PAN Jia-hui~3 1.South China Sea Institute of Oceanlogy,Chinese Academy of Sciences,Guangzhou 510301; 2.Graduate School,Chinese Academy of Sciences,Beijing 100049; 3.Department of Chemistry and Chemical Engineering,Foshan University,Foshan 528000

【机构】 中国科学院南海海洋研究所佛山科学技术学院化学与化工系 广州510301 中国科学院研究生院北京100049 佛山科学技术学院化学与化工系佛山528000广州510301 中国科学院研究生院北京100049

【摘要】 利用羧甲基壳聚糖(NOCC)复配聚丙烯酰胺(PAM)对3种水溶性染料模拟废水进行絮凝脱色处理,研究了溶液的酸度、絮凝剂与助凝剂的投加量等因素对脱色率的影响。实验结果表明,引入PAM作为助凝剂的脱色效果优于单纯使用羧甲基壳聚糖。处理此染料废水的最佳pH值为2.3,羧甲基壳聚糖的质量浓度为480mg/L,PAM投加量为4~8mg/L。在此优化条件下,复合絮凝剂对三种染料废水的脱色率为99%,COD去除率为90%;用壳聚糖/稀土复合膜处理染料废水时,对直接黑FF、还原红F3B染料废水的脱色率分别达到94.7%和98.2%,明显优于单纯壳聚糖膜。

【Abstract】 The investigation on decolorization of dyeing wastewater was conducted using a combination of coagulant,carboxymethyl chitosan(NOCC)and coagulant aid,polyscrylamide(PAM).Factors influencing the decolorization efficiency including pH value,coagulant and dosage of coagulant were discussed.Results showed that using PAM as coagulant aid could result in a high decolorization efficiency comparing with that using NOCC alone.Under the optimal conditions of pH 2.3,480mg/L for NOCC and 4~8mg/L for PAM,the rate of decolorization could achieve 99% and removal of COD 90%.The membrane process with chitosan/rare-earth metals could enhance decolorization rate of Direct Black FF to 94.7%,and Indanthrene Red F3B to 98.2% respectively.

【基金】 广东省第一批科学事业费计划项目(2006B36530002);佛山市科技发展专项基金项目(2005078B)
  • 【文献出处】 环境科学与技术 ,Environmental Science & Technology , 编辑部邮箱 ,2007年09期
  • 【分类号】X703
  • 【被引频次】38
  • 【下载频次】673
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