【摘要】 对共轭亚油酸进行三氟化硼-甲醇衍生化时,采用不同条件处理共轭亚油酸,常常导致共轭亚油酸的不完全和异构化,从而影响到分析的准确度。本文报道对化学合成共轭亚油酸的三氟化硼-甲醇衍生化方法实验研究。阐明三氟化硼在甲醇中的浓度、反应温度和反应时间对衍生化效果的影响。确定最佳衍生化条件:三氟化硼与甲醇的质量比为10∶100、反应的温度为45℃、反应时间为30 min。更多还原

【Abstract】 Deriving conjugated linoleic acid(CLA) under different condition often leads to incompletability and isomerization.It also affects the accuracy of analysis.This paper describes the experiments of CLA derivatization by boron trifluoride-methanol.Influences of derivatization condition are analyzed,such as concentration of boron trifluoride in the solution of methanol,reaction temperature and the reaction time.Following is the optimal condition: mass ratio of boron trifluoride to methanol,10∶100;temperature,45 ℃;time,30 min.更多还原