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一个新的镉卤化合物[Cd(phen)Cl2]的水热合成和晶体结构
Synthesis and crystal structure of a novel cadmium halide compound [Cd(phen) Cl2]
【摘要】 利用中温水热技术合成了一种未见报道的三维超分子化合物[Cd(phen)Cl2],并测定了其晶体结构.结果表明该化合物属于单斜晶系:C2/c空间群;晶胞参数a=16.949(3)nm,b=10.544(2)nm,c=7.226 6(14)nm,α=90°,β=110.66(3)°,γ=90°,V=1 208.4(4)nm3,Z=4,R1=0.034 1,wR2=0.083 9.
【Abstract】 A novel three dimensional supramolecular network cadmium halide compound with phen ligand was synthesized by mild hydrothermal techniques,and the synthesis and crystal structure of compound were discussed.The compound crystallized in the monoclinic,space group C2/c with a=16.949(3)nm,b=10.544(2)nm,c=7.226 6(14)nm,α=90°,β=110.66(3)°,γ=90°,V=1 208.4(4)nm3,Z=4,R1=0.034 1,wR2=0.081 6.
【关键词】 配位聚合物;
水热合成;
晶体结构;
镉卤化合物;
【Key words】 coordination polymer; hydrothermal synthesis; crystal structure; cadmium halide complex.;
【Key words】 coordination polymer; hydrothermal synthesis; crystal structure; cadmium halide complex.;
【基金】 国家自然科学基金资助项目(20371011)
- 【文献出处】 东北师大学报(自然科学版) ,Journal of Northeast Normal University(Natural Science Edition) , 编辑部邮箱 ,2007年01期
- 【分类号】O631.3
- 【被引频次】14
- 【下载频次】149