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高分子季铵盐型抗菌塑料的制备和抗菌性能

Preparation and antimicrobial properties of plastics containing nanosized SiO2 grafted with macromolecular quaternary ammonium salts

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【作者】 吴远根邱树毅张难佟会宋治福

【Author】 WU Yuangen~(1,2) QIU Shuyi~(1,2,3**) ZHANG Nan~(1,4) TONG Hui~1 SONG Zhifu~3 1.Guizhou Province Key Laboratory of Fermentation Engineering and Biopharmacy,Guizhou University,Guiyang 550003 2.College of Chemical Engineering,Guizhou University,Guiyang 550003 3.National Engineering Research Center for Compounding and Modification of Polymeric Materials,Guiyang 550014 4.College of Life Science,Guizhou University,Guiyang 550055

【机构】 贵州省发酵工程与生物制药重点实验室国家复合改性聚合物材料工程技术研究中心 贵阳 550003 贵州大学化学工程学院 贵阳 550003贵阳 550003 贵州大学化学工程学院 贵阳 550003 国家复合改性聚合物材料工程技术研究中心 贵阳 550014贵阳 550003 贵州大学生命科学学院 贵阳 550025贵阳 550003贵阳 550014

【摘要】 采用共价健合方法将高分子季铵盐接枝在纳米SiO2粉体表面,其抗细菌效果与无机载银抗菌剂相当,对金黄色葡萄球菌和大肠杆菌的最小抑菌浓度分别为100mg/L和1500mg/L.使用抗菌剂母粒化法将其添加到聚乙烯(PE)中制备抗菌塑料,抗菌粉体均匀分散在塑料的外层,平均粒径为200nm.抗菌塑料对细菌和霉菌的抗菌效果都非常显著,其防霉性能明显优于由无机载银抗菌剂制备的抗菌塑料.抗菌塑料人工老化处理不会使其抗菌效果明显下降,具有良好的抗菌长效性和稳定性.

【Abstract】 The macromolecular quaternary ammonium salts were attached covalently on the surface of nano-SiO2 to make nanometer SiO2 antimicrobial.The minimum inhibitory concentrations(MIC)of NSGMQAS against Gram-positive bacterium,Staphyococcus aureus(ATCC 6538),and Gram-negative bacterium,Eschericha coil(ATCC 25922)are 100 mg/L and 1500mg/L,respectively.Antimicrobial polythene(PE)were prepared by adding 2% antimicrobial SiO2 nanoparticles,the resultant plastics can kill more than 99% test microorganism on contact,and they also exhibit sustaining bactericidal activity after the artificial aging treatment.The antifungal activity of the PE containing antimicrobial SiO2 nanoparticles is superior to the PE containing the same addition of inorganic antimicrobial attached Ag+. The average diameter Of antimicrobial SiO2 nanoparticles is 200 nm,which dispersed equably in the outside of antimicrobial plastic.

【基金】 国家自然科学基金50363001;国家八六三计划新材料领域2003AA33X080;教育部春晖计划S2005-2-52001;贵州省自然科学基金20033082资助项目.~~
  • 【文献出处】 材料研究学报 ,Chinese Journal of Materials Research , 编辑部邮箱 ,2007年04期
  • 【分类号】TB324
  • 【被引频次】18
  • 【下载频次】891
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