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不同磷浓度对膨润土处理土壤吸附Cd2+特性的影响

Cd2+ sorption characteristics of soil treated by bentonite under different P levels

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【作者】 金美玉李博文谢建治杨华王树涛

【Author】 JIN Mei-yu,LI Bo-wen,XIE Jian-zhi,YANG Hua,WANG Shu-tao(College of Resources and Environmental Sciences,Agricultural University of Hebei,Baoding 071001,China)

【机构】 河北农业大学资源与环境学院河北农业大学资源与环境学院 河北保定071001河北保定071001

【摘要】 通过等温吸附试验,研究了P对膨润土处理土壤吸附Cd2+的影响规律。结果表明:在该试验条件下,用Freundlich方程能很好地拟合出土壤对Cd2+的吸附等温线,其相关系数r2达到了0.970以上;P对膨润土处理土壤吸附Cd2+的影响,存在正效应和负效应,并且以负效应为主;P为高浓度时,吸附常数k值明显减小,土壤对Cd2+的吸附受抑制。因此,利用膨润土治理Cd2+污染的土壤时,还应考虑P等土壤中其他成分对Cd2+的有效性的影响。

【Abstract】 Cd2+ sorption reaction in the soil treated by bentonite under different phosphorus(P) levels was investigated.Cd2+ sorption conformed the Freundlich adsorption isotherm very well.The correlation coefficient r2 reached 0.970.There were negtive and positive effect on Cd2+ sorption in soil under different phosphorus levels,whereas the negative one is dominating.The k decreased significantly at higher phosphorus concentration,that was to say the adsorption of Cd2+ was restrained.As a result,when remediating the soil contamination of Cd2+ by bentonite,we should consider nutrient element for plant such as phosphorus affect the validity of Cd2+ in soil.

【关键词】 膨润土PCd吸附反应
【Key words】 bentonitephosphorus(P)cadmium(Cd)adsorption reaction
【基金】 河北省自然科学基金项目(302340)
  • 【文献出处】 河北农业大学学报 ,Journal of Agricultural University of Hebei , 编辑部邮箱 ,2007年02期
  • 【分类号】X53
  • 【被引频次】6
  • 【下载频次】204
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