【摘要】 目的合成新型的自组装单分子膜材料巯基烷氧基喹啉化合物。方法通过羟基喹啉与1,10-二溴癸烷、硫脲反应,设计合成新的巯基烷氧基喹啉衍生物,经1H NMR和MS对其结构进行表征。结果与结论合成了2种新的巯基烷氧基喹啉衍生物即4-甲基-1-(10′-巯基-癸烷基)喹啉-2-酮和1-(10′-巯基-癸烷基)喹啉-2-酮,其结构经1H NMR和MS表征。更多还原

【Abstract】 Aim To synthesize new self-assembed monolayers(SAMs) functional materials of mercaptoalkoxy quinoline compounds.Methods The new SAMs functional materials are synthesized by reacting quinoline with 1,10-dibromodecane and thiourea,the products are characterized by 1H NMR and MS.Results and Conclusion Two new ω-mercaptoalkoxy quinoline compounds:1-(10-mercaptodecyl)-4-methyl-1H-quinoline-2-one and 1-(10mercaptodecoxy)-1H-quinoline-2-one were successfully synthesized by reacting quinoline with 1,10-dibromodecane and thiourea in alkaline solution.The intermediates and products were characterized by 1H NMR and MS.更多还原