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酸性大红GR染料废水超声降解的实验研究

Research on Ultrasonic Dgradation of Acid Brilliant Scarlet GR Dye Wastewater

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【作者】 陈长琦岑科达殷福才程建萍潘成荣郑志侠

【Author】 CHEN Chang-qi2,CEN Ke-da1,2,YIN Fu-cai1,CHENG Jian-ping2,PAN Cheng-rong1,ZHENG Zhi-xia1(1.Key Laboratory for Wastewater Research,Anhui Institute of Environmental Science,Hefei 230061,China; 2.School of Machinery and Automobile Engineering,Heifei University of Technology,Hefei 230009,China)

【机构】 合肥工业大学机械与汽车工程学院安徽省环境科学研究院污水重点实验室安徽省环境科学研究院污水重点实验室 安徽合肥230009安徽合肥230009合肥工业大学机械与汽车工程学院安徽合肥230009

【摘要】 对酸性大红GR染料模拟废水进行了超声降解研究,比较了不同浓度、不同pH值废水的超声降解效果,并对酸性大红GR染料的降解机理进行了初步探讨。实验结果表明,初始浓度为100mg/L和200mg/L的染料废水超声处理120min后,脱色效果不明显,且CODcr值分别上升20.7%和23.1%;而对于pH为3.0,初始浓度为10mg/L、30mg/L和50mg/L的染料废水,由紫外光谱测得其显色结构明显被破坏,苯环和萘环部分被打开,脱色率分别达到51.8%、36.9%和35.6%。

【Abstract】 The ultrasonic destruction to acid brilliant scarlet GR dye wastewater was studied in this paper.The effects of initial-concentration,pH value on sonolysis was compared in detail,and the decomposing mechanism was investigated.The results of experiment indicate that when the wastewater’s initial-concentration of 100mg/L and 200mg/L is ultrasonic degradation 120min,the colority of wastewater reduces almost constantly and CODcr in wastewater rises 20.7% and 23.1%.While pH value and initial-concentration is 10mg/L,30mg/L and 50mg/L,UV-Vis analysis indicates that the structure of GR is destroyed,its naphthyl and phenyl is opened partly,and the color decay rate reached 51.8%,36.9%,35.6% respectively.

  • 【文献出处】 安徽化工 ,Anhui Chemical Industry , 编辑部邮箱 ,2007年01期
  • 【分类号】X703
  • 【被引频次】13
  • 【下载频次】270
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