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B元素对正极材料LiCoO2结构及性能的影响

Effects of element B on the structure and electrochemical performance of LiCoO2 materials

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【作者】 周健戴秀珍

【Author】 ZHOU JIAN,DAI Xiu-zhen(Machinery and Electrical College,Centre South University of Forestry and Technology,Changsha 410004,China)

【机构】 中南林业科技大学机电学院中南林业科技大学机电学院 湖南长沙410004湖南长沙410004

【摘要】 为得到性能优异的锂离子电池正极材料,通过湿化学方法首先制得LiCoO2前驱体,掺入一定量H3BO3后经加热处理即得到掺B样品.通过对掺B样品进行检测分析,结果表明B的掺入能够部分改变LiCoO2的结构;其中当B含量在0.5%-3.5%时效果最好,其循环性也有提高.

【Abstract】 For getting perfect characteristic cathode material of Li-ion batteries,precursors of LiCoO2 were prepared by the method of wet-chemical,and then doping some H3BO3 in LiCoO2,the sample was acquired in a period.The structures were characterized by means of XRD,SEM and Raman Micro-Spectroscopy,the results show that the structure of LiCoO2 is changed with doping B.The electrochemical tests indicate that the sample of LiCoO2 with 2.5% B exhibit a good initial stages capacity and its cycling performance will be increased.

【关键词】 锂离子电池LiCoO2正极材料掺杂
【Key words】 Li-ion batteryLiCoO2 cathode materialdoping
  • 【文献出处】 安徽大学学报(自然科学版) ,Journal of Anhui University(Natural Sciences) , 编辑部邮箱 ,2007年02期
  • 【分类号】TM912
  • 【被引频次】21
  • 【下载频次】231
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