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Bi、Ag对Sn-Zn无铅钎料性能与组织的影响

Influence of Bi,Ag on microstructure and properties of Sn-Zn lead-free solder

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【作者】 吴文云邱小明殷世强孙大谦李明高

【Author】 WU Wen-yun,QIU Xiao-ming,YIN Shi-qiang,SUN Da-qian,LI Ming-gao(School of Materials Science and Engineering,Jilin University,Changchun 130025,China)

【机构】 吉林大学材料科学与工程学院吉林大学材料科学与工程学院 长春130025长春130025

【摘要】 研究了Bi、Ag对Sn-9Zn无铅钎料系统润湿性、接头力学性能及微观组织的影响。结果表明:Sn-9Zn无铅钎料的润湿性较差,添加适量的Bi有助于提高钎料的润湿性和接头剪切强度,但同时也使接头的塑性降低;添加适量的Ag能明显改善钎料的润湿性和接头塑性,但Ag的质量分数超过1.5%时会降低钎料润湿性和接头剪切强度。Sn-9Zn-Bi系无铅钎料组织由富Sn相、富Zn相及Bi的析出物组成;Sn-9Zn-Ag系无铅钎料组织由富Sn相、富Zn相及AgZn3化合物组成。

【Abstract】 The influences of the addition of Bi,Ag to Sn-9Zn lead-free solder on the microstructure,wettability and mechanical properties were studied.The results show that Sn-9Zn lead-free solder has poor wettability.With the addition of Bi to Sn-9Zn lead-free solder,the improvement of wettability and shearing strength of joint can be(achieved),but plasticity of joint decreases.With the addition of suitable amount Ag to Sn-9Zn lead-free solder,the improvement of wettability and plasticity of joint can be achieved obviously.With the addition of up to 1.5%Ag(mass fraction) to Sn-9Zn lead-free solder,the wettability and shearing strength of joint decreases.The micro-(structures) of Sn-9Zn-Bi solder system are composed of β-Sn matrix,Zn-rich phase and the precipitation of Bi phase in the β-Sn matrix.The microstructures of Sn-9Zn-Ag solder system are composed of β-Sn matrix,Zn-rich phase and(AgZn3) intermetallic compound.

【基金】 吉林大学创新基金资助项目(2002CX)
  • 【文献出处】 中国有色金属学报 ,The Chinese Journal of Nonferrous Metals , 编辑部邮箱 ,2006年01期
  • 【分类号】TG425
  • 【被引频次】55
  • 【下载频次】579
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