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NaCl颗粒沉积对Q235钢早期大气腐蚀的影响

EFFECT OF DEPOSITION OF NaCl ON THE INITIAL ATMOSPHERIC CORROSION OF Q235

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【作者】 肖葵董超芳李晓刚赵耀斌魏丹孙辉

【Author】 XIAO Kui~1,DONG Chaofang~1,LI Xiaogang~(1,2),ZHAO Yaobing~1,WEI Dan~3,SUN Hui~3(1.College of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083;2.State Key Laboratory for Corrosion and Protection,Shenyang 110016;3.Chinese Society for Corrosion and Protection,Beijing 100083)

【机构】 北京科技大学材料科学与工程学院中国腐蚀与防护学会中国腐蚀与防护学会 北京100083北京100083金属腐蚀与防护国家重点实验室沈阳110016

【摘要】 在实验室模拟含有5×10-6(体积分数)SO2和1%(体积分数)CO2污染成分的大气环境,采用增重法研究沉积NaCl的Q235钢的初期大气腐蚀规律.用扫描电镜和X射线衍射分析腐蚀产物.结果表明,当Q235钢表面沉积NaCl时,在SO2、CO2和NaCl的协同作用下,导致Q235钢发生严重腐蚀,腐蚀产物主要是Fe3O4,其次为γ-Fe2O3,还存在有γ-FeOOH.

【Abstract】 The influence of NaCl on the initial atmospheric corrosion of Q235 steel in simulated atmospheric environment including 5×10-6(volume) SO2 and 1%(volume) CO2 are investigated by mass gain,SEM and X-ray diffraction techniques.The results show that Q235 steel suffer a serious corrosion under the cooperative effect of NaCl,CO2 and SO2.It proved that the cooperative effect of SO2 and CO2 is important for the corrosion aggravating of Q235 steel when the NaCl is existed.The presence of NaCl accelerated and catalyzed the reaction of initial stage of atmospheric corrosion for carbon steel.The mass gain in the presence of NaCl was near decuple higher than that in the absence of NaCl.The corrosion products mainly are Fe3O4,γ-Fe2O3 and γ-FeOOH.

【基金】 国家自然科学基金项目(50499331-8)
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,2006年01期
  • 【分类号】TG172.3
  • 【被引频次】29
  • 【下载频次】373
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