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水相法制备CdS纳米棒
Preparation of CdS Nanorods in Aqueous Phase
【摘要】 采用水相法在温和的条件下,通过调节反应物的浓度、控制反应平衡,制备了泪滴状和四臂的CdS纳米棒。探讨了前驱体对合成纳米棒的影响。透射电镜观察显示,其尺寸分布较均匀、长径比可在1~7之间调节;X射线衍射图证实所制备的CdS纳米棒具有六方堆积的纤锌矿结构。
【Abstract】 Teardrop-shaped and tetrapod-shaped CdS nanocrystals were prepared in aqueous solution under mild conditions through adjusting the concentration of reactants and the equilibrium reaction.Effects of the(precursors) on nanorods were further discussed.TEM images showed that nanocrystals had a narrow size distribution and a controllable aspect ratio(1~7) to some extent,and XRD measurement confirmed the wurtzite structure for the resulting CdS nanorods.
【关键词】 CdS纳米棒;
水相溶液;
晶体生长;
乙二胺;
【Key words】 CdS nanorods; aqueous solution; crystal growth; ethylenediamine;
【Key words】 CdS nanorods; aqueous solution; crystal growth; ethylenediamine;
【基金】 国家自然科学基金(面上:90101001,50373044,20574070重点:20334010重大:50290090,20490220);中国科学院方向性项目(KJCX2-SW-H07);“九七三”项目(2003CB615600,2005CB623800);吉林省杰出青年研究计划(20050104);吉林省科技厅和长春市科技局国际合作项目(20050702-2,04-03GH268)
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2006年07期
- 【分类号】O614.242
- 【被引频次】2
- 【下载频次】205