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中国大陆科学钻探主孔0~2000米超高压变质岩中有机质的检出及成因研究

Organic matter be detected and its genic origin be studied for ultrahigh-pressure metamorphic rock from the 0-2000m main hole of the Chinese Continental Scientific Drilling Project.

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【作者】 饶竹罗立强方家虎詹秀春杨柳苏劲

【Author】 RAO Zhu, LUO LiQiang, FANG JiaHu, ZHAN XiuChun, YANG Liu and SU Jing National Research Center of Geoanalysis, Beijing 100037, China China University of Mining and Technology, Source and Safety Institution, Beijing 100083, China

【机构】 国家地质实验测试中心中国矿业大学资源与安全工程学院中国矿业大学资源与安全工程学院 北京 100037北京 100037北京 100083

【摘要】 前期研究表明大陆深钻孔区超高压变质岩经历了多期变质作用,岩石的峰期变质温度达680-850℃,压力高达1 -3GPa,如此高温、高压,理论上已接近和超过传统意义上的石油死亡线,也就是说大陆深钻孔区超高压变质岩存在有机质的可能性比较小。然而,本课题通过排除大量钻井液、泥浆、添加剂以及样品分析等过程的污染,建立起特殊样品制备和检测方法,从大陆深钻孔区0-2000米超高压变质岩中检测到了微量可溶有机质和不可溶有机质。从而为大陆深钻孔区超高压变质岩中存在有机质提供了有力证据。本文还通过对可溶有机质、不可溶有机质的特征研究如生物标志物姥姣烷、植烷和干酪根、岩心样品的Rock-Eval热解分析和有机碳分析,以及与无机成因假说对比研究认为超高压变质岩中有机质的成因为有机成因。

【Abstract】 The previous research result means that ultrahigh-pressure metamorphic rock for the Chinese Continental Scientific Drilling(CCSD) had undergone multi stages of metamorphic process and peak stage metamorphic conditions of the Sulu orogenic belt have been estimated to be 680 - 850℃and 1 - 3GPa. So ultrahigh-temperature and ultrahigh-pressure conditions that pass over dead line of organic matter of classical theory. It means that organic matter from ultrahigh-pressure metamorphic rock for the CCSD exist impossible. But actually trace amount soluble organic matter and insoluble organic matter had been detected in ultrahigh-pressure metamorphic rock for the CCSD by special sampling preparation and sampling measure method after excluding pollutions from drilling mud and additive. It synchronously confirmed that organic matter in ultrahigh-pressure metamorphic rock for the CCSD really exists. This paper also has discussed organic geochemical character such as biomarks, kerogen and Rock-Eval pyrolysis analytic result of rocks and compared with abiogenic origin theories. The conclusion that genic origin of organic matter in ultrahigh-pressure metamorphic rock for the CCSD is biogenic origin be gained.

【基金】 本文得到国家自然科学基金重大项目(编号40399144);国家重点研究发展规划(973)项目(编2003CB716508)的联合资助。
  • 【文献出处】 岩石学报 ,Acta Petrologica Sinica , 编辑部邮箱 ,2006年07期
  • 【分类号】P588.3
  • 【被引频次】4
  • 【下载频次】150
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