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沉淀法制备Nd3+掺杂改性的钛酸钡

Synthesis of Nd3+ Doped BaTiO3 by Precipitation

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【作者】 柴艮风施哲陈玉林张波

【Author】 CHAI Gen-feng,SHI Zhe,CHEN Yu-lin,ZHANG Bo(School of Materials and Metallurgy,Kunming University of Science and Technology,Kunming 650093,China)

【机构】 昆明理工大学材料与冶金学院昆明理工大学材料与冶金学院 云南昆明650093云南昆明650093

【摘要】 用共沉淀法合成了BaTiO3,研究了Ba1-xNdxTiO3系Nd3+施主一次掺杂在x=0.03~0.065之间时,BaTiO3基陶瓷电容器的本征电性能。结果表明,在此含量范围掺杂的情况下,陶瓷呈绝缘性,Nd3+含量在0.03~0.055左右时随着Nd3+含量的增加,陶瓷的ε增加,Tc呈下降趋势,tgδ值下降。Zr4+的加入也可使材料的ε增加,Tc下降。Mn2+的加入对材料的本征电性能影响不大。Ba1-3x/2NdxTiO3配比比Ba1-xNdxTiO3配比的材料的温度特性要好。

【Abstract】 Nd3+ doped BaTiO3 was synthesized by precipitation,and the electrical properties of BaTiO3 ceramic of Ba1-xNdxTiO3 with different concentration(x from 0.03 to 0.065) were investigated.Experimental results showed that BaTiO3 ceramic acted as insulator when Nd3+ was in the range of 3.0 6.5 mol%.In the range of 0.03 0.055,the(value of BaTiO3 ceramic was increased as concentration enhanced,but the Tc and tg δ were decreased.The(value also decreased when added with Zr4+,whereas there was no difference when added with Mn2+.

  • 【文献出处】 云南化工 ,Yunnan Chemical Technology , 编辑部邮箱 ,2006年02期
  • 【分类号】TQ174.4
  • 【被引频次】1
  • 【下载频次】124
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