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4-(6-羟基己氧基)联苯-4′-甲酸-L-2甲基丁醇酯的合成及其液晶性的研究
Synthesis and Study of Liquid Crystal L-2-methyl Butyl 4-[(6-hydroxylhexyl)oxy] biphenyl-4′-carbonylate
【摘要】 运用示差扫描量热仪、偏光显微镜、X射线衍射仪和计算机模拟分子链处于能量最低、最优构象时的分子长度等手段,对新合成的4-(6-羟基己氧基)联苯-4′-甲酸-L-2甲基丁醇酯进行表征。结果表明:该液晶化合物为近晶A相。合成总收率为47.3%(相对于4-羟基-4′-氰基联苯)。
【Abstract】 L-2-methyl butyl 4-[(6-hydroxylhexyl)oxy] biphenyl-4′-carbonylate were characterized by means of DSC, POM, XRD and computer simulating molecular chain length in lowest energy and optimum structure. The result shows that target molecule is smectic A phase with a total yield of 44.1 %(based on 4-hydroxyl-4′-cyanobiphenyl).
【关键词】 铁电液晶;
4-(6-羟基己氧基)联苯-4′-甲酸-L-2甲基丁醇酯;
合成;
计算机模拟;
【Key words】 ferroelectric liquid crystal; L-2-methyl butyl 4-[(6-hydroxylhexyl)oxy] biphenyl-4′-carbonylate; synthesis; computer simulation;
【Key words】 ferroelectric liquid crystal; L-2-methyl butyl 4-[(6-hydroxylhexyl)oxy] biphenyl-4′-carbonylate; synthesis; computer simulation;
【基金】 安徽省“十五”攻关项目(No.200183)
- 【文献出处】 液晶与显示 ,Chinese Journal of Liquid Crystals and Displays , 编辑部邮箱 ,2006年01期
- 【分类号】TN104.3
- 【被引频次】4
- 【下载频次】143