【摘要】 缬氨霉素为中性载体的PVC膜铷离子选择电极有较好的选择性,KpRotb,K=0.35。该电极已用于铷的分析测定和含Rb+的水和醇水体系的热力学性质的研究。更多还原

【Abstract】 PVC membrane rubidium ion electrodes with valinomycin as neutral ionophore was prepared and its selective coefficient K^pot_Rb,K=0.35.Determination of rubidium in some aqueous samples by the potentiometric method,known dilution-standard addition and potentiometric precipitation titration has been developed.The activity coefficients for RbCl and Rb₂SO₄ aqueous and nonaqueous（MeOH+H₂O）mixtures were determined by electromotive force measurements with the electrodes.更多还原