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工艺条件对稀土掺杂玻璃紫外线屏蔽性能的影响

Effect of Processing Condition on UV Shielding of Glass Containing Rare Earth

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【作者】 赵洪力韩冰蔡永秀张福成

【Author】 Zhao Hongli1,2*,Han Bing1,Cai Yongxiu1,Zhang Fucheng1,2(1.College of Materials Science & Engineering,Yanshan University,Qinhuangdao 066004,China;2.Key Laboratory of Metastable Materials Science & Technology,Hebei,Yanshan University,Qinhuangdao 066004,China)

【机构】 燕山大学材料科学与工程学院燕山大学材料科学与工程学院 河北秦皇岛066004河北省亚稳材料制备技术与科学重点实验室燕山大学河北秦皇岛066004

【摘要】 研究了在玻璃中掺杂铈和钕对玻璃的紫外线屏蔽能力的影响,分析了其紫外线吸收的机制。结果表明,紫外线屏蔽能力与稀土元素添加量有明显的依赖关系,随着添加量的增加,紫外线的透过率均呈降低趋势,在同样添加量时,氧化钕比氧化铈的屏蔽能力强;随着保温时间的不同,含氧化铈玻璃的屏蔽能力有所不同,而含氧化钕的玻璃对保温时间不敏感。

【Abstract】 The ultraviolet ray shielding ability of common glasses and glasses containing cerium(Ce) or neodymium(Nd) at different concentration were compared.The mechanism of UV shielding of glasses containing rare-earth ions were discussed.The experimental results reveals that there are strong relationship between UV shielding abilities and additive quantity.UV transmittance shows decrease as increase of additive quantity.The UV shielding ability of glass containing neodymium oxide is better than cerium at same concentration.The influence of different heat preservation conditions to UV shielding glasses were also analyzed.UV shielding abilities containing cerium oxide are differ as differ heat preservation time,but neodymium oxide is little sensitivity.

【关键词】 玻璃紫外线稀土
【Key words】 glassesUV cutceriumneodymiumrare earths
【基金】 河北省教育厅自然科学指令计划项目(2005304)资助
  • 【文献出处】 中国稀土学报 ,Journal of the Chinese Rare Earth Society , 编辑部邮箱 ,2006年S2期
  • 【分类号】TQ171.1
  • 【被引频次】2
  • 【下载频次】221
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