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膨胀次数对天然鳞片膨胀石墨微结构的影响
Effect of expansion time on the microstructure of an expanded natural flake graphite
【摘要】 借助于N2物理吸附、XRD和SEM对经多次膨胀后的天然鳞片石墨进行了研究,研究结果表明:随着膨胀次数的增加,石墨膨胀前后的松装密度的差别越来越小。在多次膨胀过程中,第一次膨胀时鳞片石墨比表面积增加量最大,后续的膨胀对石墨比表面积的影响逐渐减小。鳞片石墨经过五次膨胀后,d004和d101分别有约千分之二和千分之四的增加,多次膨胀石墨仍由石墨微晶构成。多次膨胀后石墨为蓬松状的粉末,在微观结构中出现了类似于揉搓纸团的结构。
【Abstract】 The changes of bulk density,specific surface area and microstructure of natural flake graphite after several expansions were studied by nitrogen adsorption,XRD and SEM.Results show that the differences in bulk density get smaller and smaller with increasing expansion time.The increase of specific surface area in the first expansion is much bigger than in following expansions.The lattice parameters of the graphite change very(slightly),with d004 and d101 increasing by only about 0.2 % and 0.4 % respectively after five expansions.SEM images show that the expanded graphite appears like crumpled paper in an expanded state.
【Key words】 Multi-expanded graphite; Bulk density; Specific surface area; Microstructure;
- 【文献出处】 新型炭材料 ,New Carbon Materials , 编辑部邮箱 ,2006年02期
- 【分类号】O613.71
- 【被引频次】21
- 【下载频次】379