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高性能芳纶浆粕/HNBR复合材料的制备及性能研究

Preparation and properties of aramid pulp/HNBR composite

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【作者】 任玉柱; 刘力; 吴卫东; 曹建莉; 钦焕宇; 张立群;

【Author】 REN Yu-zhu~1,LIU Li~1,WU Wei-dong~1,CAO Jian-li~1,QIN Huan-yu~2,ZHANG Li-qun~1(1.Beijing University of Chemical Technology,Beijing 100029,China;2.Fujin Rubber Co.Ltd,Fujin 156100,China)

【机构】 北京化工大学北京市新型高分子材料制备与成型加工重点实验室; 北京化工大学纳米材料先进制备技术与应用科学教育部重点实验室; 富锦市橡胶有限责任公司; 北京化工大学北京市新型高分子材料制备与成型加工重点实验室 北京100029; 北京100029; 黑龙江富锦156100;

【摘要】 试验研究预处理方法对芳纶浆粕在橡胶基体中分散性及芳纶浆粕/HNBR复合材料性能的影响。结果表明,芳纶浆粕预处理改善了其在复合材料中的分散效果;白炭黑预处理复合材料的定伸应力和拉伸强度提高,拉断伸长率减小,高温下物理性能稍有改善;共沉法预处理改善效果不明显;白炭黑预处理芳纶浆粕用量增大,混炼时间不变,复合材料物理性能提高,但高温下撕裂强度减小;芳纶浆粕/HNBR复合材料中,芳纶浆粕容易取向;芳纶浆粕用量增大,复合材料挤出性能改善。

【Abstract】 The influence of the pretreating method on the dispersion of aramid pulp in rubber matrix and the properties of aramid pulp/HNBR composite was experimentally investigated.The results showed that the dispersion of aramid pulp in composite was improved by the pretreatment of aramid pulp;the modulus and tensile strength of composite increased when the aramid pulp was pretreated with silica,at the same time the elongation at break decreased and the physical properties at high temperature improved a little;the improvement was not remarkable as the aramid pulp was pretreated by coprecipitation method;as the proportion of silica-pretreated aramid pulp increased and the mixing time kept constant,the physical properties of composite increased,but the tear strength at high temperature decreased;the aramid was easily oriented in the aramid pulp/HNBR composite;and the extrudability of compound improved as the proportion of aramid pulp increased.

【基金】 国家“八六三”计划资助项目(2003AA333060)
  • 【文献出处】 橡胶工业 ,China Rubber Industry , 编辑部邮箱 ,2006年02期
  • 【分类号】TQ330.7
  • 【被引频次】24
  • 【下载频次】393
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