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液化石油气制芳烃技术开发及工业应用

Technological development and commercial application of liquefied petroleum gas in aromatics

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【作者】 郝代军朱建华王国良龚旭辉王宗泉

【Author】 HAO Dai-jun~1,2,ZHU Jian-hua~1,WANG Guo-liang~1,2,GONG Xu-hui~2,WANG Zong-quan~3(1.College of Chemical Engineering,China University of Petroleum,Beijing 102249,China;2.Luoyang Petrochemical Engineering Corporation,SINOPEC, Luoyang 471003,China;3.Shandong Hengyuan Petrochemical Group,Linyi 251500, China)

【机构】 中国石油大学化工学院中国石化集团洛阳石油化工工程公司山东恒源石油化工集团 北京102249河南洛阳471003北京102249山东临邑251500

【摘要】 采用组合固定床反应-再生系统和改性HZSM-5分子筛催化剂,开发出利用液化石油气制芳烃工艺(GTA)。该工艺可将液化石油气转化为苯、甲苯和二甲苯等轻质芳烃,而且流程简单,操作稳定,所产混合芳烃不含非芳烃组分,简化了抽提流程,节省了投资,并降低了能耗。4.0万t/a的工业化装置运行结果表明:利用GTA技术能将醚化后的C4组分转化为质量分数56.76%的芳烃,同时还能得到质量分数为23.74%的民用液化气。

【Abstract】 Liquefied petroleum gas(LPG) can be converted into light aromatics,such as benzene,toluene and xylene by using modified HZSM-5 zeolite catalyst and GTA process which adopts the fixed-bed reaction-regeneration system.The process is feasible,with short flow and stable running.Since no non-aromatic components exist in the GTA products,the aromatic extraction equipment is eliminated in the GTA process.The operating results demonstrated that for a commercial plant with the capacity of 40kt/a,with the feedstock of C4 after etherified,the yield of light aromatics can be up to 56.76%,and the yield of household LPG can reach 23.74% simultaneously.

  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2006年10期
  • 【分类号】TQ241.1
  • 【被引频次】27
  • 【下载频次】504
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