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有机粘土基多孔颗粒材料的制备及其特性研究
PREPARATIONS AND CHARACTERISTICS OF ORGANOCLAY-BASED POROUS PARTICLE MATERIALS
【摘要】 研究了海藻酸钠(SA)与HDTMA改性的蒙脱土(HDTMAmodifiedmontmorillonite,HMM)的颗粒化制备及其与石油烃降解菌的复合,并研究了SA∶HMM不同质量比及不同SA浓度、不同CaCl2浓度下HMM颗粒的水稳性和吸油性、降解菌活性等性质。结果表明,在SA浓度为1%~2%,CaCl2浓度为2%~4%,SA∶HMM=1∶10时,获得的HMM颗粒粒径为2.5~4.0mm,对HMM表面结构影响不大,吸油率可达原始HMM的80%;将HMM颗粒与石油烃降解菌复合可形成稳定的生物膜,膜厚度为300μm左右,生物量为40~50mg·g-1。HMM颗粒复合生物膜为油污染地下水化学吸附生物降解提供了一种尝试。
【Abstract】 HDTMA-modified montmorillonite (HMM) was immobilized by SA-CaCl2 to form granulated organoclay. Moreover, the granulated HMM was incubated with oil-depredated microorganisms and the stable biofilm was formed on the surface. The HMM composed with calcium alginate in solution at SA concentration of 1%2%, at CaCl2 concentration of 2%4%, and ratio of SA∶HMM at 1∶10. The granulated HMM could exist 30 d to 150 d steadily under 200 r/min vibration in water and its oil-adsorbed capability maintained 80% of original HMM. After finishing incubation oil-depredated microorganisms with granulated HMM, a stabile biofilm formed at 4050 mg·g -1 of biomass and 300 μm of thickness, and also showed high enzyme activity.
【Key words】 granulated organoclay; sodium alginate; oil adsorption; biofilm;
- 【文献出处】 陕西科技大学学报 ,Journal of Shaanxi University of Science & Technology , 编辑部邮箱 ,2006年02期
- 【分类号】TB383.4
- 【下载频次】108