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溴酸钾氧化二甲基黄动力学光度法测定食品中的痕量硒(Ⅳ)

Kinetic Spectrophotometric Determination of Trace Selenium(Ⅳ) Based on Discoloring of Dimethyl Yellow Oxidized by Potassium Bromate

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【作者】 王黎周之荣罗明标

【Author】 WANG Li,ZHOU Zhi-rong~*,LUO Ming-biao(Department of Applied Chemistry,East China Institute of Technology,Fuzhou 344000,China)

【机构】 东华理工学院应用化学系东华理工学院应用化学系 江西抚州344000江西抚州344000

【摘要】 基于0.004 mol/L的HNO3介质中,在乳化剂OP存在时,痕量硒(Ⅳ)催化溴酸钾氧化二甲基黄的褪色反应,建立了测定痕量硒(Ⅳ)的催化光度法。方法检出限为0.015μg/L,线性范围为0~0.8μg/L,加标回收率为98.0%~102.5%,样品测定的相对标准偏差(RSD)为2.6%~7.2%。用于测定食品中的痕量硒(Ⅳ)时,结果满意。

【Abstract】 Based on the catalytic effect of trace selenium(Ⅳ) on discoloring reaction of dimethyl yellow with potassium bromate in 0.004mol/L nitric acid solution and in the presence of OP emulsifier,a method for determination of trace selenium(Ⅳ) by kinetic spectrophotometry has been developed. The detection limit is 0.015 μg/L and the linear range of determination is 0~0.8 μg/L for tin.The recoveries are 98.0%~102.5%,and the relative standard deviation(RSD) is 2.6%~7.2%.Combined solvent extract separation,the method has been applied to the determination of trace selenium(Ⅳ) in foodstuffs samples with satisfactory results.

【基金】 江西省自然科学基金项目(0520002);华东理工学院院长基金项目(DHY0449)
  • 【文献出处】 食品与生物技术学报 ,Journal of Food Science and Biotechnology , 编辑部邮箱 ,2006年01期
  • 【分类号】TS207.5
  • 【被引频次】2
  • 【下载频次】87
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