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直接模板法合成三维立方介孔氧化硅HOM-5

Preparation of 3D Cubic Mesoporous Silica HOM-5 via Direct-templating Synthesis

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【作者】 苗小郁李健生赵江艳王连军孙秀云刘晓东

【Author】 MIAO Xiao-Yu LI Jian-Sheng ZHAO Jiang-Yan WANG Lian-Jun* SUN Xiu-Yun LIU Xiao-Dong(Department of Environmental Science and Engineering,Nanjing University of Science and Technology,Nanjing 210094)

【机构】 南京理工大学环境科学与工程系南京理工大学环境科学与工程系 南京210094南京210094

【Abstract】 Highly ordered mesoporous silica HOM-5(cubic,Ia3d)with three-dimensional(3D)bicontinuous channels was fabricated under acidic condition via a direct-templating synthesis.Primary lyotropic liquid crystal mesophase of P123 was used as the template.The as-synthesized HOM-5 had thick walls of 15.0 nm.The mean pore diameter and specific surface area of the material were 5.7 nm and 500 m2·g-1,respectively.Results show that materials obtained from this simple synthesis are highly ordered with perfect meso-structures.The results of hydrothermal testing show that the as-synthesized silica retains Ia3d space group after refluxing in boiling water for 6 hours.

【关键词】 直接模板法介孔氧化硅HOM-5
【Key words】 direct-templating synthesismesoporous silicaHOM-5
【基金】 江苏省自然科学基金(No.BK2006205);南京理工大学青年学者基金资助项目(No.njust200502)资助项目。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2006年11期
  • 【分类号】O613.72
  • 【被引频次】2
  • 【下载频次】177
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