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稀土气相扩渗法制备钕-氮化钼及其导电性

Preparation and Conductivity of Nd-MoN by Rare Earth Gas Phase Permeation

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【作者】 李昕吴丽平郭元茹

【Author】 LI Xin*,1 WU Li-Ping1 GUO Yuan-Ru2 (1Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001) (2College of Material Science and Engineering, Northeast Forestry University, Harbin 150040)

【机构】 哈尔滨工业大学应用化学系东北林业大学材料科学与工程学院 哈尔滨150001哈尔滨150001哈尔滨150040

【Abstract】 Nd-doped MoN was prepared by thermal permeation of rare earth Nd in MoN using FeMo6 as the precursor. XRD, DTA, XPS and XRF have been used to characterize the FeMo6 precursor and the thermal treated samples. XRD, XPS and XRF results show that FeMo6 structure is decomposed and Nd-doped MoN is formed during the thremal treatment. XPS results also give the evidence that it is Nd3+ ion that can be permeated into the bulk of MoN. The conductivity of MoN is increased from 0.228 S·cm-1 to 2.649 × 102 S·cm-1 by Nd doping.

【关键词】 稀土气相扩渗钕-氮化钼导电性
【Key words】 rare earths co-permeationNd-MoNconduction
【基金】 国家自然科学基金资助项目(No.20371014)
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2006年10期
  • 【分类号】O614.33
  • 【被引频次】2
  • 【下载频次】140
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