节点文献
由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O(英文)
One-dimensional Chain Polyoxotungstate Decorated with Amino Acid Copper Complex: (H3O)3{Na3(H2O)13(Cu(Gly)2)2(H2W12O42)}·11H2O
【Abstract】 A new compound, (H3O)3{Na3(H2O)13(Cu(Gly)2)2(H2W12O42)}·11H2O (1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid ligand. Two cis-{Cu(Gly)2}2+ engraft into the (H2W12O42)10- with Cu-O bond of 0.241 2(7) nm, and Na+ ions linked these (Cu(Gly)2)2(H2W12O42)6- clusters into a one-dimensional chain. CCDC: 278000.
【关键词】 有机无机杂化材料;
水热合成;
晶体结构;
钨多酸;
氨基酸;
【Key words】 organic-inorganic hybrid; hydrothermal synthesis; crystal structure; polyoxotungstate; amino acid;
【Key words】 organic-inorganic hybrid; hydrothermal synthesis; crystal structure; polyoxotungstate; amino acid;
【基金】 973项目(No.001CB108906);国家自然科学基金资助项目(No.20425313,90206040,20333070,20303021,20521101);福建省自然科学基金资助项目(No.2005HZ01-1)
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2006年08期
- 【分类号】O627;O641.4
- 【被引频次】4
- 【下载频次】104