【摘要】 作为潜在的新型功能材料,硼-锗骨架微孔化合物近年来得到科学家的普遍关注。本文从结构化学的角度,分别讨论了硼酸盐、锗酸盐及硼锗酸盐研究体系,并对其中的典型结构进行了描述、归类与总结;针对硼、锗易成簇聚集的特点,探讨了硼-锗骨架无机微孔化合物研究的发展趋势。更多还原

【Abstract】 As a new type of potential functional materials, microporous inorganic solids with boron and germanate elements have attracted much attention in the last few years. In this paper, the progress in the synthetic and typical structural chemistry of borates, germanates and borogermanates, has been reviewed in detail. The new prospects of such materials have also been discussed, considering the construction of inorganic materials with B-O, Ge-O and B-Ge-O clusters.更多还原