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纳米SrTiO3对高铁酸盐电化学性能影响研究
Nanometer SrTiO3 Effect on Electrochemical Performance of Ferrate Electrode
【Abstract】 Two ferrates, K2FeO4 and BaFeO4, had been prepared and characterized by XRD, IR and SEM. The electrochemical tests of the samples were carried out in the voltage range of 0.8~2.0 V and current density of 0.5~3.0 mA·cm-2. The results indicated that performance of Zn-BaFeO4 battery was superior to that of Zn-MnO2 and Zn-K2FeO4 batteries. Nanometer SrTiO3 prepared by Sol-gel methode with different ratio was added to the BaFeO4 cathode in order to improve the discharge performance. The discharge capacity of the BaFeO4 cathode was increased from 224 mAh·g-1 to 246 mAh·g-1 by addition of 5% nanometer SrTiO3. The reason of enhancing BaFeO4 electrochemical performance was discussed.
【关键词】 K2FeO4;
BaFeO4;
SrTiO3;
电化学性能;
【Key words】 K2FeO4; BaFeO4; SrTiO3; electrochemical performance;
【Key words】 K2FeO4; BaFeO4; SrTiO3; electrochemical performance;
【基金】 四川省基础应用研究基金资助项目(No.川教科9902)。
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2006年06期
- 【分类号】O646
- 【被引频次】6
- 【下载频次】100