节点文献
2-羟基萘甲醛苯甲酰腙作配体的钼和钒两个化合物的合成和晶体结构(英文)
Synthesis and Structures of Molybdenum and Vanadium Two Complexes with 2-Hydroxy Naphthaldehyde Benzoylhydrazone Ligand (H2L)
【摘要】 2-羟基萘甲醛苯甲酰腙(H2L)由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得。利用H2L分别合成了钼和钒的配合物,[MoO2(EtOH)L](1)和[VO(OMe)L(MeOH)](2),并测定了它们的晶体结构。配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位构型。
【Abstract】 The new aroyl-hydrazone ligand, 2-Hydroxy naphthaldehyde benzoylhydrazone (H2L), was prepared by the reaction of 2-Hydroxy naphthaldehyde and benzoyhydrazine in an ethanol solution. Two complexes, MoO2 (EtOH)L (1) and VO(OMe)L(MeOH) (2), based on the H2L ligand have been synthesized and characterized by single crystal X-ray diffraction analysis. Complexes 1 and 2 exhibit analogous structural units, the metal atom in which has a distorted octahedral coordination geometry. CCDC: 298811 (1), 298810 (2).
【关键词】 2-羟基萘甲醛苯甲酰腙;
钼和钒;
合成和结构;
【Key words】 2-hydroxy naphthaldehyde benzoylhydrazone; molybdenum and vanadium; synthesis and structure;
【Key words】 2-hydroxy naphthaldehyde benzoylhydrazone; molybdenum and vanadium; synthesis and structure;
【基金】 国家自然科学基金资助项目(No.90206040,20333070,20303021);973资助项目(001CB108906);福建省自然科学基金资助(No.2005HZ01-1)。
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2006年06期
- 【分类号】O641.4
- 【被引频次】7
- 【下载频次】181